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trimethyl borate 121-43-7 SAFETY DATA SHEETS

2018.09.11 Category:Company profile Share  

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of

Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name trimethyl borate

1.2 Other means of identification

Product number-

Other names Trimthyl borate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.

Uses advised againstno data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number-

Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Flammable liquids, Category 3

Acute toxicity - Dermal, Category 4

2.2 GHS label elements, including precautionary statements

Pictogram(s)

Signal word Warning

Hazard statement(s)

H226 Flammable liquid and vapour

H312 Harmful in contact with skin

Precautionary

statement(s)

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

Prevention P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or

shower].

P370+P378 In case of fire: Use ... to extinguish.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P312 Call a POISON CENTER/doctor/…if you feel unwell.

P321 Specific treatment (see ... on this label).

P362+P364 Take off contaminated clothing and wash it before reuse.

Storage P403+P235 Store in a well-ventilated place. Keep cool.

Disposal P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS numberEC numberConcentration

trimethyl borate trimethyl borate 121-43-7 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel

to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide

appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government

standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous

substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable

laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive

89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state A water-white liquid

Colour no data available

Odour no data available

Melting point/ freezing point 209°C(lit.)

Boiling point or initial boiling point and boiling range 68-69°C(lit.)

Flammability no data available

Lower and upper explosion limit / flammability limit no data available

Flash point -8°C

Auto-ignition temperature no data available

Decomposition temperature no data available

pH no data available

Kinematic viscosity no data available

Solubility In water:reacts

Partition coefficient n-octanol/water (log value) no data available

Vapour pressure no data available

Density and/or relative density 0.932g/mLat 20°C(lit.)

Relative vapour density 3.59 (vs air)

Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

11.Toxicological information

Acute toxicity

Oral: no data available

Inhalation: no data available

Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

Toxicity to fish: no data available

Toxicity to daphnia and other aquatic invertebrates: no data available

Toxicity to algae: no data available

Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not

contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it

unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible

packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN2416IMDG: UN2416IATA: UN2416

14.2 UN Proper Shipping Name

ADR/RID: TRIMETHYL BORATE

IMDG: TRIMETHYL BORATE

IATA: TRIMETHYL BORATE

14.3 Transport hazard class(es)

ADR/RID: 3IMDG: 3IATA: 3

14.4 Packing group, if applicable

ADR/RID: IIIMDG: IIIATA: II

14.5 Environmental hazards

ADR/RID: noIMDG: noIATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS number EC number

trimethyl borate trimethyl borate 121-43-7 none

European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.

EC Inventory Listed.

United States Toxic Substances Control Act (TSCA) Inventory Listed.

China Catalog of Hazardous chemicals 2015 Listed.

New Zealand Inventory of Chemicals (NZIoC) Listed.

Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.

Vietnam National Chemical Inventory Not Listed.

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)Listed.

16.Other information

Information on revision

Creation Date Aug 10, 2017

Revision Date Aug 10, 2017

Abbreviations and acronyms

CAS: Chemical Abstracts Service

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road

RID: Regulation concerning the International Carriage of Dangerous Goods by Rail

IMDG: International Maritime Dangerous Goods

IATA: International Air Transportation Association

TWA: Time Weighted Average

STEL: Short term exposure limit

LC50: Lethal Concentration 50%

LD50: Lethal Dose 50%

EC50: Effective Concentration 50%

References

IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:

http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this

document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any

guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.