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1-ethoxy-2-(2-ethoxyethoxy)ethane112-36-7 SAFETY DATA SHEETS

2018.09.03 Category:Company profile Share  

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of

Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-ethoxy-2-(2-ethoxyethoxy)ethane

1.2 Other means of identification

Product number-

Other names Ethane, 1,1‘-oxybis[2-ethoxy-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Processing aids, not otherwise listed

Uses advised againstno data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number-

Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)

Signal word Warning

Hazard statement(s) H315 Causes skin irritation

Precautionary statement(s)

Prevention

P264 Wash ... thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Response

P302+P352 IF ON SKIN: Wash with plenty of water/...

P321 Specific treatment (see ... on this label).

P332+P313 If skin irritation occurs: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

none

Storage

none

Disposal none

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name Common names and synonyms CAS numberEC numberConcentration

1-ethoxy-2-(2-ethoxyethoxy)ethane1-ethoxy-2-(2-ethoxyethoxy)ethane112-36-7 none 100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

Fresh air, rest.

In case of skin contact

Remove contaminated clothes. Rinse skin with plenty of water or shower.

In case of eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

If swallowed

Rinse mouth.

4.2 Most important symptoms/effects, acute and delayed

SYMPTOMS: Symptoms of exposure to this compound include irritation of the skin, eyes, mucous membranes and respiratory tract, coughing,

dyspnea and kidney damage. Other symptoms may include nausea, vomiting, headache and central nervous system depression. Exposure may also

cause diarrhea, abdominal and lumbar pain, mild liver damage, pulmonary edema, transient polyuria, oliguria, anuria and death by acute renal

failure. ACUTE/CHRONIC HAZARDS: This compound may be harmful by inhalation, ingestion or skin absorption. It is an irritant of the skin,

eyes, mucous membranes and respiratory tract. When heated to decomposition it emits acrid smoke, irritating fumes and toxic fumes of carbon

monoxide and carbon dioxide.

4.3 Indication of immediate medical attention and special treatment needed, if necessary

Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of

respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary

edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination,

flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion,

rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool.

Administer activated charcoal ... . /Ethylene glycol, glycols, and related compounds/

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.

5.2 Specific hazards arising from the chemical

This chemical is combustible.

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel

to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Collect leaking liquid in sealable containers. Wash away remainder with plenty of water.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide

appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Separated from strong oxidants. Ventilation along the floor.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government

standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous

substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable

laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive

89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state colourless liquid

Colour Colorless liquid

Odour no data available

Melting point/ freezing point -44.3oC

Boiling point or initial boiling point and boiling range 180-190°C(lit.)

Flammability Combustible.

Lower and upper explosion limit / flammability limit no data available

Flash point 67°C

Auto-ignition temperature 205°C

Decomposition temperature no data available

pH no data available

Kinematic viscosity no data available

Solubility In water:SOLUBLE

Partition coefficient n-octanol/water (log value) log Kow = 0.39

Vapour pressure 0.5 mm Hg ( 20 °C)

Density and/or relative density 0.909g/mLat 25°C(lit.)

Relative vapour density 5.6 (vs air)

Particle characteristics no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Extremely stable

10.3 Possibility of hazardous reactions

CombustibleDIETHYLENE GLYCOL DIETHYL ETHER is incompatible with strong acids. It is also incompatible with strong oxidizing agents.

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

Glycol ethers, glycols, ketones, and alcohols undergo violent decomposition in contact with 68-72% perchloric acid

10.6 Hazardous decomposition products

When heated to decomposition it emits acrid smoke and irritating fumes.

11.Toxicological information

Acute toxicity

Oral: LD50 Rat oral 4970 mg/kg

Inhalation: no data available

Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

Toxicity to fish: no data available

Toxicity to daphnia and other aquatic invertebrates: no data available

Toxicity to algae: no data available

Toxicity to microorganisms: no data available

12.2 Persistence and degradability

AEROBIC: An aerobic biodegradation study using gram-negative asporogenous rod bacterium isolated from soil by enrichment on triethylene

glycol exhibited borderline growth (scarcely detectable growth, not reproducible) with diethylene glycol diethyl ether(1). In a screening study using

a sewage seed, diethylene glycol diethyl ether (concentration not specified) had a 10 day BOD of 0.10 g/g (4.2% theoretical BOD) at 20°C(2).

Diethylene glycol diethyl ether had a 21.7% COD removal at 30°C from a starting concentration of 600 mg COD/L (time period not given)

indicating little degradation compared to 95% degradation of ethylene glycol monophenyl ether(3).

12.3 Bioaccumulative potential

An estimated BCF of 3 was calculated in fish for diethylene glycol diethyl ether(SRC), using a log Kow of 0.39(1) and a regression-derived

equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4 Mobility in soil

The Koc of diethylene glycol diethyl ether is estimated as 39(SRC), using a log Kow of 0.39(1) and a regression-derived equation(2). According

to a classification scheme(3), this estimated Koc value suggests that diethylene glycol diethyl ether is expected to have very high mobility in soil.

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not

contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it

unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible

packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: no data availableIMDG: no data availableIATA: no data available

14.2 UN Proper Shipping Name

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.3 Transport hazard class(es)

ADR/RID: no data availableIMDG: no data availableIATA: no data available

14.4 Packing group, if applicable

ADR/RID: no data availableIMDG: no data availableIATA: no data available

14.5 Environmental hazards

ADR/RID: noIMDG: noIATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name Common names and synonyms CAS numberEC number

1-ethoxy-2-(2-ethoxyethoxy)ethane1-ethoxy-2-(2-ethoxyethoxy)ethane112-36-7 none

European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.

EC Inventory Listed.

United States Toxic Substances Control Act (TSCA) Inventory Listed.

China Catalog of Hazardous chemicals 2015 Not Listed.

New Zealand Inventory of Chemicals (NZIoC) Listed.

Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.

Vietnam National Chemical Inventory Listed.

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Listed.

16.Other information

Information on revision

Creation Date Aug 12, 2017

Revision Date Aug 12, 2017

Abbreviations and acronyms

CAS: Chemical Abstracts Service

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road

RID: Regulation concerning the International Carriage of Dangerous Goods by Rail

IMDG: International Maritime Dangerous Goods

IATA: International Air Transportation Association

TWA: Time Weighted Average

STEL: Short term exposure limit

LC50: Lethal Concentration 50%

LD50: Lethal Dose 50%

EC50: Effective Concentration 50%

References

IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:

http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this

document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any

guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.