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malononitrile 109-77-3 SAFETY DATA SHEETS

2018.08.23 Category:Company profile Share  

  SAFETY DATA SHEETS

  According to Globally Harmonized System of Classification and Labelling of

  Chemicals (GHS) - Sixth revised edition

  Version: 1.0

  Creation Date: Aug 13, 2017

  Revision Date: Aug 13, 2017

  1.Identification

  1.1 GHS Product identifier

  Product name malononitrile

  1.2 Other means of identification

  Product number-

  Other names Propanedinitrile

  1.3 Recommended use of the chemical and restrictions on use

  Identified uses For industry use only. Intermediates

  Uses advised againstno data available

  1.4 Supplier's details

  1.5 Emergency phone number

  Emergency phone number-

  Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

  2.Hazard identification

  2.1 Classification of the substance or mixture

  Acute toxicity - Oral, Category 3

  Acute toxicity - Dermal, Category 3

  Acute toxicity - Inhalation, Category 3

  Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1

  Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1

  2.2 GHS label elements, including precautionary statements

  Pictogram(s)

  Signal word Danger

  Hazard statement(s)

  H301 Toxic if swallowed

  H311 Toxic in contact with skin

  H331 Toxic if inhaled

  H410 Very toxic to aquatic life with long lasting effects

  Precautionary statement(s)

  Prevention

  P264 Wash ... thoroughly after handling.

  P270 Do not eat, drink or smoke when using this product.

  P280 Wear protective gloves/protective clothing/eye protection/face protection.

  P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

  P271 Use only outdoors or in a well-ventilated area.

  P273 Avoid release to the environment.

  Response

  P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

  P321 Specific treatment (see ... on this label).

  P330 Rinse mouth.

  P302+P352 IF ON SKIN: Wash with plenty of water/...

  P312 Call a POISON CENTER/doctor/…if you feel unwell.

  P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

  P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

  P311 Call a POISON CENTER/doctor/…

  P391 Collect spillage.

  Storage

  P405 Store locked up.

  P403+P233 Store in a well-ventilated place. Keep container tightly closed.

  Disposal P501 Dispose of contents/container to ...

  2.3 Other hazards which do not result in classification

  none

  3.Composition/information on ingredients

  3.1 Substances

  Chemical name Common names and synonyms CAS numberEC numberConcentration

  malononitrile malononitrile 109-77-3 none 100%

  4.First-aid measures

  4.1 Description of necessary first-aid measures

  General advice

  Consult a physician. Show this safety data sheet to the doctor in attendance.

  If inhaled

  Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. Half-upright position.

  In case of skin contact

  Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

  In case of eye contact

  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

  If swallowed

  Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two

  glasses of water to drink. Refer for medical attention .

  4.2 Most important symptoms/effects, acute and delayed

  Metabolized by body to cyanide and thiocyanate; effects of inhalation of toxic fumes will be related to cyanide. Causes brain and heart damage

  related to lack of cellular oxygen. It is classified as extremely toxic. Probable oral lethal dose for humans is 5-50 mg/kg, or between 7 drops and 1

  teaspoonful, for a 70 kg (150 lb.) person. (EPA, 1998)

  4.3 Indication of immediate medical attention and special treatment needed, if necessary

  Rapid support of respiration and circulation is essential to successful treatment of cyanide intoxication. Massive cyanide overdoses have survived

  with only good supportive care. Immediate attention should be directed toward assisted ventilation, administration of 100% oxygen, insertion of

  intravenous lines, and institution of cardiac monitoring. Obtain an arterial blood gas immediately and correct any severe metabolic acidosis (pH

  below 7.15). Oxygen (100%) should be used routinely in moderate or severely symptomatic patients even in the presence of a normal pO2, since

  100% O2 increases O2 delivery, may reactivate cyanide-inhibited mitochondrial enzymes, and potentiates the effect of thiosulfate. Avoid mouth to

  mouth resuscitation during CPR in order to prevent self poisoning. /Cyanides/

  5.Fire-fighting measures

  5.1 Extinguishing media

  Suitable extinguishing media

  To fight fire, use water, fog, spray, foam.

  5.2 Specific hazards arising from the chemical

  When heated to decomposition, malononitrile emits highly toxic fumes (cyanide). May polymerize violently on prolonged heating. Avoid heat.

  Hazardous polymerization may occur, at prolonged heating at 266F or contact with strong bases at lower temperatures. (EPA, 1998)

  5.3 Special protective actions for fire-fighters

  Wear self-contained breathing apparatus for firefighting if necessary.

  6.Accidental release measures

  6.1 Personal precautions, protective equipment and emergency procedures

  Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel

  to safe areas. Avoid breathing dust. For personal protection see section 8.

  6.2 Environmental precautions

  Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical

  enter the environment. Vacuum spilled material with specialist equipment. If appropriate, moisten first to prevent dusting.

  6.3 Methods and materials for containment and cleaning up

  Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  7.Handling and storage

  7.1 Precautions for safe handling

  Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide

  appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

  7.2 Conditions for safe storage, including any incompatibilities

  Cool. Separated from strong bases and food and feedstuffs. Well closed. Keep in a well-ventilated room.

  8.Exposure controls/personal protection

  8.1 Control parameters

  Occupational Exposure limit values

  Recommended Exposure Limit: 10 Hr Time-Weighted avg: 3 ppm (8 mg/cu m).

  Biological limit values

  no data available

  8.2 Appropriate engineering controls

  Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

  8.3 Individual protection measures, such as personal protective equipment (PPE)

  Eye/face protection

  Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government

  standards such as NIOSH (US) or EN 166(EU).

  Skin protection

  Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous

  substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without

  touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable

  laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive

  89/686/EEC and the standard EN 374 derived from it.

  Respiratory protection

  Wear dust mask when handling large quantities.

  Thermal hazards

  no data available

  9.Physical and chemical properties

  Physical state Solidified melt

  Colour Colorless solid

  Odour no data available

  Melting point/ freezing point 30-34oC

  Boiling point or initial boiling point and boiling range 220oC

  Flammability Combustible SolidCombustible.

  Lower and upper explosion limit / flammability limit no data available

  Flash point 112oC

  Auto-ignition temperature no data available

  Decomposition temperature no data available

  pH no data available

  Kinematic viscosity no data available

  Solubility In water:13.3 g/100 mL (20 oC)

  Partition coefficient n-octanol/water (log value) log Kow = -0.60

  Vapour pressure 0.125mmHg at 25°C

  Density and/or relative density 1.049

  Relative vapour density (air = 1): 2.3

  Particle characteristics no data available

  10.Stability and reactivity

  10.1 Reactivity

  no data available

  10.2 Chemical stability

  The stability of the molten nitrile decreases with increasing temperature and decreasing purity, but no violent decomposition at below 100°C has

  been recorded.

  10.3 Possibility of hazardous reactions

  Combustible when exposed to heat or flame.MALONONITRILE is a white, low-melting powder (m. p. 30.5° C), toxic, combustible. Violent

  polymerization on contact with strong bases (sodium hydroxide, potassium hydroxide) or when heated above 130° C. When stored at 70-80° C

  for 2 months, spontaneous explosion (decomposition) occurred [Bretherick, 5th ed., 1995, p. 394].

  10.4 Conditions to avoid

  no data available

  10.5 Incompatible materials

  Strong bases [Note: May polymerize violently on prolonged heating at 265 degrees F, or in contact with strong bases at lower temperatures].

  10.6 Hazardous decomposition products

  When heated to decomposition it emits toxic fumes of NOx and CN- /nitrogen oxides and cyanides/.

  11.Toxicological information

  Acute toxicity

  Oral: LD50 Mouse oral 19 mg/kg

  Inhalation: no data available

  Dermal: no data available

  Skin corrosion/irritation

  no data available

  Serious eye damage/irritation

  no data available

  Respiratory or skin sensitization

  no data available

  Germ cell mutagenicity

  no data available

  Carcinogenicity

  no data available

  Reproductive toxicity

  no data available

  STOT-single exposure

  no data available

  STOT-repeated exposure

  no data available

  Aspiration hazard

  no data available

  12.Ecological information

  12.1 Toxicity

  Toxicity to fish: LC50 Rainbow trout 1.6 mg/l/96 hr /Conditions of bioassay not specified

  Toxicity to daphnia and other aquatic invertebrates: no data available

  Toxicity to algae: no data available

  Toxicity to microorganisms: no data available

  12.2 Persistence and degradability

  AEROBIC: Nitriles are biodegraded by enzyme-catalyzed hydrolysis to ultimately form carboxylic acids and ammonia(1,2). Thus, malononitrile

  may biodegrade in the environment(SRC).

  12.3 Bioaccumulative potential

  An estimated BCF of 3 was calculated for malononitrile(SRC), using a log Kow of -0.60(1) and a regression-derived equation(2). According to a

  classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

  12.4 Mobility in soil

  The Koc of malononitrile is estimated as 11(SRC), using a measured log Kow of -0.60(1) and a regression-derived equation(2). According to a

  classification scheme(3), this estimated Koc value suggests that malononitrile is expected to have very high mobility in soil(SRC).

  12.5 Other adverse effects

  no data available

  13.Disposal considerations

  13.1 Disposal methods

  Product

  The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not

  contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

  Contaminated packaging

  Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it

  unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible

  packaging materials.

  14.Transport information

  14.1 UN Number

  ADR/RID: UN2647IMDG: UN2647IATA: UN2647

  14.2 UN Proper Shipping Name

  ADR/RID: MALONONITRILE

  IMDG: MALONONITRILE

  IATA: MALONONITRILE

  14.3 Transport hazard class(es)

  ADR/RID: 6.1IMDG: 6.1IATA: 6.1

  14.4 Packing group, if applicable

  ADR/RID: IIIMDG: IIIATA: II

  14.5 Environmental hazards

  ADR/RID: yesIMDG: yesIATA: yes

  14.6 Special precautions for user

  no data available

  14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

  no data available

  15.Regulatory information

  15.1 Safety, health and environmental regulations specific for the product in question

  Chemical name Common names and synonyms CAS number EC number

  malononitrile malononitrile 109-77-3 none

  European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.

  EC Inventory Listed.

  United States Toxic Substances Control Act (TSCA) Inventory Listed.

  China Catalog of Hazardous chemicals 2015 Listed.

  New Zealand Inventory of Chemicals (NZIoC) Listed.

  Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.

  Vietnam National Chemical Inventory Not Listed.

  Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)Listed.

  16.Other information

  Information on revision

  Creation Date Aug 13, 2017

  Revision Date Aug 13, 2017

  Abbreviations and acronyms

  CAS: Chemical Abstracts Service

  ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road

  RID: Regulation concerning the International Carriage of Dangerous Goods by Rail

  IMDG: International Maritime Dangerous Goods

  IATA: International Air Transportation Association

  TWA: Time Weighted Average

  STEL: Short term exposure limit

  LC50: Lethal Concentration 50%

  LD50: Lethal Dose 50%

  EC50: Effective Concentration 50%

  References

  IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

  HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

  IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

  eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:

  http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

  CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

  ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

  ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

  Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

  ECHA - European Chemicals Agency, website: https://echa.europa.eu/

  Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this

  document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any

  guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.