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Propyl chloroformate 109-61-5 SAFETY DATA SHEETS

2018.08.22 Category:Company profile Share  

  SAFETY DATA SHEETS

  According to Globally Harmonized System of Classification and Labelling of

  Chemicals (GHS) - Sixth revised edition

  Version: 1.0

  Creation Date: Aug 10, 2017

  Revision Date: Aug 10, 2017

  1.Identification

  1.1 GHS Product identifier

  Product name Propyl chloroformate

  1.2 Other means of identification

  Product number-

  Other names Chloroformic Acid Propyl Ester

  1.3 Recommended use of the chemical and restrictions on use

  Identified uses For industry use only.

  Uses advised againstno data available

  1.4 Supplier's details

  1.5 Emergency phone number

  Emergency phone number-

  Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

  2.Hazard identification

  2.1 Classification of the substance or mixture

  Flammable liquids, Category 2

  Skin corrosion, Category 1B

  Acute toxicity - Inhalation, Category 3

  2.2 GHS label elements, including precautionary statements

  Pictogram(s)

  Signal word Danger

  Hazard statement(s)

  H225 Highly flammable liquid and vapour

  H314 Causes severe skin burns and eye damage

  H331 Toxic if inhaled

  Precautionary

  statement(s)

  P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

  Prevention

  P233 Keep container tightly closed.

  P240 Ground and bond container and receiving equipment.

  P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

  P242 Use non-sparking tools.

  P243 Take action to prevent static discharges.

  P280 Wear protective gloves/protective clothing/eye protection/face protection.

  P260 Do not breathe dust/fume/gas/mist/vapours/spray.

  P264 Wash ... thoroughly after handling.

  P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

  P271 Use only outdoors or in a well-ventilated area.

  Response

  P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or

  shower].

  P370+P378 In case of fire: Use ... to extinguish.

  P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

  P363 Wash contaminated clothing before reuse.

  P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

  P310 Immediately call a POISON CENTER/doctor/…

  P321 Specific treatment (see ... on this label).

  P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

  easy to do. Continue rinsing.

  P311 Call a POISON CENTER/doctor/…

  Storage

  P403+P235 Store in a well-ventilated place. Keep cool.

  P405 Store locked up.

  P403+P233 Store in a well-ventilated place. Keep container tightly closed.

  Disposal P501 Dispose of contents/container to ...

  2.3 Other hazards which do not result in classification

  none

  3.Composition/information on ingredients

  3.1 Substances

  Chemical name Common names and synonyms CAS numberEC numberConcentration

  Propyl chloroformatePropyl chloroformate 109-61-5 none 100%

  4.First-aid measures

  4.1 Description of necessary first-aid measures

  General advice

  Consult a physician. Show this safety data sheet to the doctor in attendance.

  If inhaled

  Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.

  In case of skin contact

  Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

  In case of eye contact

  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

  If swallowed

  Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .

  4.2 Most important symptoms/effects, acute and delayed

  Strongly irritating to eyes and mucous membranes. Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. (EPA, 1998)

  4.3 Indication of immediate medical attention and special treatment needed, if necessary

  no data available

  5.Fire-fighting measures

  5.1 Extinguishing media

  Suitable extinguishing media

  If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of

  water may be ineffective. Apply water from as far a distance as possible. Use "alcohol" foam, carbon dioxide or dry chemical. Keep run-off water

  out of sewers and water sources.

  5.2 Specific hazards arising from the chemical

  When heated to decomposition, it emits toxic fumes of chlorine containing compounds. Propyl chloroformate is a flammable/combustible material;

  it may be ignited by heat, sparks or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat or fire. Vapor

  explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Runoff from fire control or

  dilution water may cause pollution. Gradually decomposed by water and alcohol. Unstable, decomposes spontaneously to form hydrochloric acid

  and other products. Avoid moist air. (EPA, 1998)

  5.3 Special protective actions for fire-fighters

  Wear self-contained breathing apparatus for firefighting if necessary.

  6.Accidental release measures

  6.1 Personal precautions, protective equipment and emergency procedures

  Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel

  to safe areas. Avoid breathing dust. For personal protection see section 8.

  6.2 Environmental precautions

  Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let

  this chemical enter the environment. Collect leaking and spilled liquid in sealable dry plastic containers as far as possible. Absorb remaining liquid in

  dry sand or inert absorbent. Then store and dispose of according to local regulations.

  6.3 Methods and materials for containment and cleaning up

  Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  7.Handling and storage

  7.1 Precautions for safe handling

  Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide

  appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

  7.2 Conditions for safe storage, including any incompatibilities

  Fireproof. Provision to contain effluent from fire extinguishing. Separated from acids, alcohols, amines, bases, oxidants and food and feedstuffs.

  Dry. Well closed. Store in an area without drain or sewer access.OWING TO THE FACT THAT THESE COMPOUNDS DECOMP

  EASILY, STORAGE CONTAINERS SHOULD BE VENTED. /CHLOROFORMATES/

  8.Exposure controls/personal protection

  8.1 Control parameters

  Occupational Exposure limit values

  no data available

  Biological limit values

  no data available

  8.2 Appropriate engineering controls

  Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

  8.3 Individual protection measures, such as personal protective equipment (PPE)

  Eye/face protection

  Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government

  standards such as NIOSH (US) or EN 166(EU).

  Skin protection

  Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous

  substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without

  touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable

  laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive

  89/686/EEC and the standard EN 374 derived from it.

  Respiratory protection

  Wear dust mask when handling large quantities.

  Thermal hazards

  no data available

  9.Physical and chemical properties

  Physical state colorless to light yellow transparent liquid

  Colour COLORLESS LIQUID

  Odour no data available

  Melting point/ freezing point 11°C(lit.)

  Boiling point or initial boiling point and boiling range 115°C(lit.)

  Flammability Flammable. Gives off irritating or toxic fumes (or gases) in a fire.

  Lower and upper explosion limit / flammability limit no data available

  Flash point 28°C(lit.)

  Auto-ignition temperature 475°C

  Decomposition temperature no data available

  pH no data available

  Kinematic viscosity 0.80 cP @ 20°C

  Solubility MISCIBLE WITH BENZENE, CHLOROFORM, ETHER

  Partition coefficient n-octanol/water (log value) 1.12

  Vapour pressure 0.87 psi ( 20 °C)

  Density and/or relative density 1.09

  Relative vapour density 4.2 (EPA, 1998) (Relative to Air)

  Particle characteristics no data available

  10.Stability and reactivity

  10.1 Reactivity

  no data available

  10.2 Chemical stability

  THEY TEND TO DECOMP SPONTANEOUSLY TO FORM HYDROCHLORIC ACID & OTHER PRODUCTS /CHLOROFORMATES/

  10.3 Possibility of hazardous reactions

  Unstable, decomposes spontaneously to form hydrochloric acid and other products. Avoid moist air. [EPA, 1998]. May react vigorously or

  explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

  10.4 Conditions to avoid

  no data available

  10.5 Incompatible materials

  no data available

  10.6 Hazardous decomposition products

  no data available

  11.Toxicological information

  Acute toxicity

  Oral: no data available

  Inhalation: no data available

  Dermal: no data available

  Skin corrosion/irritation

  no data available

  Serious eye damage/irritation

  no data available

  Respiratory or skin sensitization

  no data available

  Germ cell mutagenicity

  no data available

  Carcinogenicity

  no data available

  Reproductive toxicity

  no data available

  STOT-single exposure

  no data available

  STOT-repeated exposure

  no data available

  Aspiration hazard

  no data available

  12.Ecological information

  12.1 Toxicity

  Toxicity to fish: no data available

  Toxicity to daphnia and other aquatic invertebrates: no data available

  Toxicity to algae: no data available

  Toxicity to microorganisms: no data available

  12.2 Persistence and degradability

  no data available

  12.3 Bioaccumulative potential

  no data available

  12.4 Mobility in soil

  no data available

  12.5 Other adverse effects

  no data available

  13.Disposal considerations

  13.1 Disposal methods

  Product

  The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not

  contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

  Contaminated packaging

  Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it

  unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible

  packaging materials.

  14.Transport information

  14.1 UN Number

  ADR/RID: UN2740IMDG: UN2740IATA: UN2740

  14.2 UN Proper Shipping Name

  ADR/RID: n-PROPYL CHLOROFORMATE

  IMDG: n-PROPYL CHLOROFORMATE

  IATA: n-PROPYL CHLOROFORMATE

  14.3 Transport hazard class(es)

  ADR/RID: 6.1IMDG: 6.1IATA: 6.1

  14.4 Packing group, if applicable

  ADR/RID: IIIMDG: IIIATA: II

  14.5 Environmental hazards

  ADR/RID: noIMDG: noIATA: no

  14.6 Special precautions for user

  no data available

  14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

  no data available

  15.Regulatory information

  15.1 Safety, health and environmental regulations specific for the product in question

  Chemical name Common names and synonyms CAS number EC number

  Propyl chloroformate Propyl chloroformate 109-61-5 none

  European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.

  EC Inventory Listed.

  United States Toxic Substances Control Act (TSCA) Inventory Listed.

  China Catalog of Hazardous chemicals 2015 Listed.

  New Zealand Inventory of Chemicals (NZIoC) Listed.

  Philippines Inventory of Chemicals and Chemical Substances (PICCS) Listed.

  Vietnam National Chemical Inventory Not Listed.

  Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)Listed.

  16.Other information

  Information on revision

  Creation Date Aug 10, 2017

  Revision Date Aug 10, 2017

  Abbreviations and acronyms

  CAS: Chemical Abstracts Service

  ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road

  RID: Regulation concerning the International Carriage of Dangerous Goods by Rail

  IMDG: International Maritime Dangerous Goods

  IATA: International Air Transportation Association

  TWA: Time Weighted Average

  STEL: Short term exposure limit

  LC50: Lethal Concentration 50%

  LD50: Lethal Dose 50%

  EC50: Effective Concentration 50%

  References

  IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

  HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

  IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

  eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website:

  http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

  CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

  ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

  ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

  Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

  ECHA - European Chemicals Agency, website: https://echa.europa.eu/

  Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this

  document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any

  guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.